Breaking paracyclophane: the unexpected formation of non-symmetric disubstituted nitro [2.2] metaparacyclophanes

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dc.citation.volume17
dc.contributor.authorPatel S
dc.contributor.authorDais TN
dc.contributor.authorPlieger PG
dc.contributor.authorRowlands GJ
dc.coverage.spatialGermany
dc.date.accessioned2023-12-15T01:13:57Z
dc.date.accessioned2024-07-25T06:36:42Z
dc.date.available2021-06-29
dc.date.available2023-12-15T01:13:57Z
dc.date.available2024-07-25T06:36:42Z
dc.date.issued2021
dc.description.abstractSubstituted [2.2]metaparacyclophanes are amongst the least studied of the simple cyclophanes. This is undoubtedly the result of the lengthy syntheses of these compounds. We report the simple synthesis of a rare example of a non-symmetric [2.2]metaparacyclophane. Treatment of [2.2]paracyclophane under standard nitration conditions gives a mixture of 4-nitro[2.2] paracyclophane, 4-hydroxy-5-nitro [2.2] metaparacyclophane and a cyclohexadienone cyclophane.
dc.format.pagination1518-1526
dc.identifier.author-urlhttps://www.ncbi.nlm.nih.gov/pubmed/34285723
dc.identifier.citationPatel S, Dais TN, Plieger PG, Rowlands GJ. (2021). Breaking paracyclophane: the unexpected formation of non-symmetric disubstituted nitro[2.2]metaparacyclophanes.. Beilstein J Org Chem. 17. (pp. 1518-1526).
dc.identifier.doi10.3762/bjoc.17.109
dc.identifier.eissn1860-5397
dc.identifier.elements-typejournal-article
dc.identifier.issn1860-5397
dc.identifier.urihttps://mro.massey.ac.nz/handle/10179/70534
dc.languageeng
dc.publisherBeilstein-Institut
dc.relation.isPartOfBeilstein J Org Chem
dc.rights(c) The author/sen
dc.rights.licenseCC BY 4.0en
dc.rights.urihttps://creativecommons.org/licenses/by/4.0/en
dc.subjectcyclophane
dc.subjectmetaparacyclophane
dc.subjectnitration
dc.subjectparacyclophane
dc.subjectrearrangement
dc.titleBreaking paracyclophane: the unexpected formation of non-symmetric disubstituted nitro [2.2] metaparacyclophanes
dc.typeJournal article
pubs.elements-id447508
pubs.organisational-groupOther
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